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84388-01
French patent application FR0002272 filed on February 2nd 2000 and entitled: « Method for obtaining macroscopic fibres and strips from colloidal particles and in particular carbon nanotubes »
Philippe POULIN
Brigitte VIGOLO
Alain PENICAUD
Claude COULON
Research agreement, exclusive or non exclusive licenses
Centre de Recherche Paul Pascal (C.R.P.P./ UPR8641), Pessac, France.
The invention concerns a method for obtaining fibres and strips from colloidal particles, characterised in that it consists in: dispersing said particles in a solvent optionally using a surfactant; injecting the resulting dispersion solution through at least an orifice emerging into a flow of an external solution, preferably, having a higher viscosity than said dispersion, the viscosity levels being measured in the same temperature and pressure conditions, so as to cause said particles to agglomerate into fibres or strips by destabilising the particle dispersions and optionally aligning said particles.
The invention concerns a method for obtaining fibres and strips from colloidal particles, characterised in that it consists in: dispersing said particles in a solvent optionally using a surfactant; injecting the resulting dispersion solution through at least an orifice emerging into a flow of an external solution, preferably, having a higher viscosity than said dispersion, the viscosity levels being measured in the same temperature and pressure conditions, so as to cause said particles to agglomerate into fibres or strips by destabilising the particle dispersions and optionally aligning said particles.
Philippe POULIN’s patent has been considered as relevant by examiners for the following invention:
– WO02055769 Honeywell Int. Inc.
– WO03069032 DSM NV.
– JP2003301333 DENSO Corp.
– JP2004010614 OREAL
– WO2004074558 Nanoledge SA.
– WO2004112164 Nanoledge SA.
– EP1612187 Dupont
– EP1873281 DSM IP ASSETS
The process is especially useful for producing fibers or ribbons from carbon nanotubes, preferably comprising one or more concentric graphite cylinders, optionally chemically modified by grafting, to obtain products useful for reinforcing fiber-based materials, tapes or cables; for fabricating conductors, semiconductors and insulators for electronic and microelectronic applications; in electron emission systems, especially displays; as artificial muscles and electromechanical actuators; and for making textiles or cables; as well as in the manufacture of optical and electrooptic devices; catalysts and catalyst supports; electrodes; hydrogen storage systems for batteries; tips for tunnel effect and atomic force microscopes; filter membranes; chemical sensors; and biomedical materials, e.g. prostheses, tendons and ligaments.
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